期刊
ORGANIC LETTERS
卷 13, 期 1, 页码 30-33出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol102422h
关键词
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资金
- Dartmouth College
- Burke Research Initiation Award
A hydrazone-based rotary switch, having a quinolinyl stator and a pyridine ring as part of the rotor, can be induced using pH to undergo a four-step switching sequence. This process yields three stable isomers and a fourth metastable one that can all be addressed separately based on the sequence of acid and base added. The switching process proceeds via conformational and/or configurational changes, allowing the molecule to rotate around two different axles.
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