期刊
ORGANIC LETTERS
卷 14, 期 2, 页码 656-659出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol203353a
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资金
- DFG (IRTG Munster-Nagoya)
- European Research Council under the European Community [25936]
- Alfried Krupp von Bohlen und Halbach Foundation
An efficient Rh(III)-catalyzed direct C-H amination of N-pivaloyloxy benzamides with N-chloroamines proceeding at room temperature was achieved. The versatile directing group allows for selective mono- and diamination and can be readily converted to give valuable benzamide or aminoaniline derivatives. Mechanistic studies have been carried out to elucidate the reaction pathway.
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