期刊
ORGANIC LETTERS
卷 13, 期 6, 页码 1394-1397出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol2000815
关键词
-
资金
- University of Geneva
- Swiss NSF
[CpRu(CH3CN)(3)][PF6] and dilmine ligands catalyze together the decomposition of alpha-diazocarbonyl compounds leading to O-H insertion and condensation reactions. In comparison with Rh(II) and Cu(I) complexes, the CpRu catalysts produce rapid and often more selective reactions. Promising enantioselectivities are obtained in dioxole syntheses.
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