期刊
ORGANIC LETTERS
卷 13, 期 19, 页码 5116-5119出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol201984s
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资金
- MICINN [CTQ2010-14882, CTQ2009-13699, CTQ2009-11027, JCI-2010-06204]
- UPV [20100994]
The feasibility of an electron transfer imino-Diels-Alder reaction between N-benzylideneaniline and arylalkenes in the presence of a pyrylium salt as a photosensitizer has been demonstrated by a combination of product studies, laser flash photolysis (LFP), and DFT theoretical calculations. A stepwise mechanism involving two intermediates and two transition states is proposed.
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