期刊
ORGANIC LETTERS
卷 13, 期 22, 页码 6046-6049出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol202520x
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资金
- National Basic Research Program of China [2011CB808705]
- National Natural Science Foundation of China [20732005]
- Shanghai Municipal Committee of Science [08dj-1400100]
A first practical Ni(0)-catalyzed highly stereoselective methyl-carboxylation of homopropargylic alcohols with ZnMe2 and CO2 for the efficient synthesis of alpha-alkylidene-gamma-butyrolactones is described. The reaction may be applied to other alkynols.
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