期刊
ORGANIC LETTERS
卷 13, 期 12, 页码 2984-2987出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol200696q
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资金
- University of North Carolina at Greensboro
The reaction of acetylides with sulfonyl azides was found to selectively form 1,5-substituted sulfonyl triazoles. This reaction thus provides access to the regioisomeric product as compared to the popular copper-catalyzed azide-alkyne cycloaddition. The reaction is efficient and selective with a variety of alkyne sources and sulfonyl azides and can incorporate an additional electrophile to yield 1,4,5-trisubstituted sulfonyl triazoles.
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