期刊
ORGANIC LETTERS
卷 13, 期 4, 页码 764-767出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol103018v
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-
资金
- NSFC [20674004]
- ISTCP [2008DFA61420]
- 111 project [B08002]
A straightforward synthesis of triphenylene-perylene-triphenylene triad structures has been achieved by using versatile triphenylene intermediates bearing a single oxyalkyl amine side chain. Among these, PBITP10 showed a stable columnar mesophase implying favorably matched core-core separations in the structure. Importantly, the triad can be used as a vehicle for doping columnar triphenylene matrices with functional but incompatible perylene units and a mixture of hexahexyloxytriphenylene matrix doped with 0.1% PBITP10 is homogeneous and liquid crystalline.
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