期刊
ORGANIC LETTERS
卷 13, 期 7, 页码 1690-1693出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol200194y
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资金
- Fonds der Chemischen Industrie
- European Research Council (ERC)
- Deutsche Forschungsgemeinschaft (DFG)
- Center of Advanced Studies, Ludwig Maximilians-Universitat Munchen (CAS)
Using TMPZnCl center dotLiCl as a kinetically highly active base, nitriles and esters undergo a Pd-catalyzed alpha-arylation under mild conditions. Remarkably, in the case of alpha,beta or beta,gamma-unsaturated nitriles, a regioselective gamma-arylation or a gamma-alkenylation is observed.
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