期刊
ORGANIC LETTERS
卷 13, 期 12, 页码 2992-2995出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol200799u
关键词
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资金
- MEXT, Japan [21685011]
- Chemistry of Nagoya University
- Asahi Glass Foundation
- JSPS
- World Class University [R32-2010-000-10217]
- Ministry of Education, Science, and Technology (MEST) of Korea
- Grants-in-Aid for Scientific Research [21685011] Funding Source: KAKEN
Treatment of a meso-arylboron dipyrrin (BODIPY) with NBS provides mono- and dibromlnated BODIPYs at the 2- and 6-positions In excellent yields with high regioselectivity. Brominated products can be employed as a nice building block for the synthesis of a variety of BODIPY derivatives through Suzuki-Miyaura coupling. Because of a lack of substituents at the 1,3,5,7-positions, a directly beta-beta-linked BODIPY dimer exhibits a completely coplanar conformation of BODIPY units, offering effective pi-conjugation.
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