期刊
ORGANIC LETTERS
卷 13, 期 10, 页码 2580-2583出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol200684b
关键词
-
资金
- National Natural Science Foundation of China [2080-2085]
- Chinese Academy of Sciences
A novel iron-catalyzed alkenylation of 2-substituted azaarenes through sp(3) C-H bond activation has been developed. A favorable E2-elimination Is proposed as a key step to cleavage of C-H and C-N bonds for the construction of a C=C bond in high stereoselectivity. This transformation represents an efficient way to synthesize 2-alkenylated azaarenes from simple starting materials.
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