期刊
ORGANIC LETTERS
卷 13, 期 22, 页码 6026-6029出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol202493c
关键词
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资金
- Singapore DSTA [DSTANUS-DIRP/2008/03]
- NRF [R-143-000-360-281]
- A*Star BMRC [10/1/21/19/642]
- KAUST
An anthracene unit was successfully fused to the zigzag edge of a boron dipyrromethene (BODIPY) core by an FeCl3-mediated oxidative cyclodehydrogenation reaction. Meanwhile, a dimer was also formed by both intramolecular cyclization and intermolecular coupling. The anthracene-fused BODIPY monomer la and dimer 7b showed small energy gaps (similar to 1.4 eV) and near-Infrared absorption/emission. Moreover, they exhibited high photostability.
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