期刊
ORGANIC LETTERS
卷 13, 期 17, 页码 4570-4573出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol2017627
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资金
- Japan Society of the Promotion of Science [22550122]
- Funding Program for Next Generation World-Leading Researchers [GR067]
- Grants-in-Aid for Scientific Research [23245026, 22550122] Funding Source: KAKEN
6-O-Modified beta-cyclodextrins, such as heptakis(6-O-triisopropylsilyl)-beta-cyclodextrin (TIPS-beta-CD) and heptakis(6-O-tert-butyldimethylsilyl)-beta-cyclodextrin (TBDMS-beta-CD), formed 2:1 Inclusion complexes with pyrene in benzene and cyclohexane with high association constants. The X-ray crystalline structure of the TIPS-beta-CD-pyrene complex obtained from the benzene solution showed that one pyrene molecule was incorporated in the form of a sandwich-type complex with two benzene molecules within the cavity of the dimer formed by two TIPS-beta-CD molecules.
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