期刊
ORGANIC LETTERS
卷 13, 期 15, 页码 3872-3875出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol201403m
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-
资金
- Dept of Chemistry and Biochemistry, the College of Arts and Sciences
Three Cucurbit[7]uril-controlled chemiluminescent on/off switches based on the lucigenin motif have been synthesized. Light emission Is triggered upon addition of sodium peroxide, interrupted or dimmed in the presence of Cucurbit[7]uril, and restored upon injection of a competitive guest. The process, which can be mimicked by a simple resistor-capacitor circuit, is rationalized by examining the role of the macrocyclic host on the network of equilibria involved in the chemiluminescent process.
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