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ORGANIC LETTERS
卷 13, 期 24, 页码 6350-6353出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol202527g
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资金
- National Basic Research Program of China (973 program) [2011CB808600]
- National Natural Science Foundation of China [21172221]
- Chinese Academy of Sciences
A chiral phosphoric acid catalyzed enantioselective bromocyclization of olefins is described. Various cis-, trans-, or trisubstituted gamma-hydroxy-alkenes and gamma-amino-alkenes can cyclize under the reaction conditions to give optically active 2-substituted tetrahydrofurans and tetrahydropyrroles in up to 91% ee.
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