期刊
ORGANIC LETTERS
卷 13, 期 23, 页码 6264-6267出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol202740w
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资金
- University of British Columbia
- Natural Sciences and Engineering Research Council of Canada
A new photoinduced electron-transfer-promoted redox fragmentation of N-alkoxyphthalimides has been developed. Mechanistic experiments have established that this reaction proceeds through a unique concerted intramolecular fragmentation process. This distinctive mechanism imparts many synthetic advantages, which are highlighted in the redox fragmentation of various heterocyclic substrates.
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