期刊
ORGANIC LETTERS
卷 13, 期 4, 页码 680-683出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol102916b
关键词
-
资金
- Australian Postgraduate Award
The total synthesis of the 43 amino acid antibacterial peptide Microcin B17 (MccB17) is described. The natural product was synthesized via a convergent approach from a heterocycle-derived peptide and peptide thioester fragments prepared via Fmoc-strategy solid phase peptide synthesis (SPPS). Final assembly was achieved in an efficient manner using two Ag(I)-assisted peptide ligation reactions to afford MccB17 in excellent overall yield.
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