期刊
ORGANIC LETTERS
卷 13, 期 14, 页码 3596-3599出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol201205t
关键词
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资金
- Asahi Glass Foundation
- [B21390030]
- [22106515]
- Grants-in-Aid for Scientific Research [10J08891, 21390030, 22106515] Funding Source: KAKEN
Copper-mediated chemoselective trifluoromethylation at the benzylic :position by the use of shelf-stable electrophilic trifluoromethylating reagents 3 in good to high yields under mild conditions is described for the first time. The generality of this trifluoromethylation for a wide variety of benzyl bromides facilitates the rapid creation of structural diversity of medicinal candidates in drug discovery.
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