期刊
ORGANIC LETTERS
卷 13, 期 13, 页码 3320-3323出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol201028f
关键词
-
资金
- French Agence Nationale de la Recherche [ANR07-CP2D-CA-SAL-04-01]
- University of Nice - Sophia Antipolis
- CNRS
Nonactivated trienes and aryltrienes were cyclized into polycyclic compounds in good to excellent yields under bismuth triflate catalysis in a biomimetic fashion. The reaction showed broad applicability and allowed for the formation of functionalized bicyclic to tetracyclic structures from simple precursors in one pot. For some specific substrates, the cyclization was followed by a methyl shift as encountered in terpenoid biosynthesis.
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