期刊
ORGANIC LETTERS
卷 13, 期 23, 页码 6152-6155出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol2024604
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资金
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- NSFC [20802047, 21072142]
A new N-sulfonyl formamidine synthesis was developed via Nal-catalyzed direct condensation of sulfonamide and formamide. The green methodology is featured by high atom economy, easily available starting materials, the lack of need for a transition-metal catalyst, no requirement of hazardous reagent, operational simplicity, and good tolerance with diverse functional groups. Mechanistic studies suggest that the protocol proceeds based upon in situ generated TsN center dot Nal.
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