期刊
ORGANIC LETTERS
卷 13, 期 14, 页码 3664-3666出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol201477u
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资金
- University of Wisconsin-Madison
A stereoselective total synthesis of (-)-kumausallene was completed in 12 steps from acetylacetone. The hidden symmetry of (-)-kumausallene was recognized, and its skeleton was constructed efficiently from a C(2)-symmetric diol by a palladium-catalyzed cascade reaction. High diastereoselectivity was observed for the DMF-promoted biomimetic 1,4-bromocyclization of a conjugated enyne.
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