4.8 Article

Palladium-Catalyzed Oxidative Carbocyclization/Arylation of Enallenes

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ORGANIC LETTERS
卷 13, 期 21, 页码 5838-5841

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AMER CHEMICAL SOC
DOI: 10.1021/ol202451f

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资金

  1. European Research Council (ERC) [AdG 247014]
  2. Swedish Research Council
  3. Berzelius center EXSELENT
  4. C. F. Liljevalch J:ors travel grant

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A stereoselective palladium-catalyzed oxidative carbocyclization/arylation of enallenes is described. The reaction shows wide tolerance toward highly functionalized arylboronic acids and results In a cis addition of two carbon moieties to an olefin in good to excellent yields.

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