期刊
ORGANIC LETTERS
卷 13, 期 11, 页码 2928-2931出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol2009818
关键词
-
资金
- NIGMS [GM077170]
- NSF [CHE-0547566]
It is reported that stable glycosyl sulfonium salts can be generated via direct anomeric S-methylation of ethylthioglycosides. Mechanistically, this pathway represents the first step in the activation of thioglycosides for glycosidation; however, it can further allow for the synthesis and isolation of quasi-stable sulfonium ions, representing a new approach for studying these key intermediates.
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