期刊
ORGANIC LETTERS
卷 13, 期 17, 页码 4578-4580出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol201705k
关键词
-
资金
- National Institutes of Health, National Institute of General Medical Sciences [GM087620]
- National Science Foundation [CHE-0848982]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0848982] Funding Source: National Science Foundation
Sulfamoyl azides are readily generated from secondary amines and a novel sulfonyl azide transfer agent, 2,3-dimethyl-1H-imidazolium triflate. They react with alkynes in the presence of a CuTC catalyst forming 1-sulfamoyl-1,2,3-triazoles. The latter are shelf-stable progenitors of rhodium azavinyl carbenes, versatile reactive intermediates that, among other reactions, readily and asymmetrically add to olefins.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据