期刊
ORGANIC LETTERS
卷 13, 期 12, 页码 3250-3253出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol2011874
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资金
- CNRS
- F. Hoffmann-La Roche AG
A highly efficient Pd-catalyzed P-C coupling reaction of easily accessible atropisomeric bisphosphane is described in the presence of various electron-poor aromatic iodides. The reactions are conducted in the presence of a Pd(II)/dppf catalyst in acetonitrile at 80 degrees C. The reaction conditions are compatible with several electron-withdrawing groups such as esters, cyano, chloro, and trifluoromethyl groups and lead to atropisomeric MeOBIPHEP derivatives in good to excellent yields and high enantiomeric purities.
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