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卷 13, 期 24, 页码 6398-6401出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol202705g
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资金
- National Natural Science Foundation of China [20902025, 21172075]
- Shanghai Pujiang Program [10PJ1403100]
- 973 Program [2011CB808600]
It is reported that Hg(ClO4)(2)center dot 3H(2)O could efficiently activate the cheap but less reactive allyltrimethylsilane for the allylation of isatins or isatin ketoimines, with catalyst loading down to 0.1 mol %. This is the first example of Sakurai-Hosomi allylation of ketoimines using allyltrimethylsilane. A rare example of chiral mercury catalysis is also reported.
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