期刊
ORGANIC LETTERS
卷 13, 期 24, 页码 6584-6587出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol202957d
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资金
- National Science Foundation [CHE-0911192]
- Amgen
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0911192] Funding Source: National Science Foundation
alpha-Amino acids react with aldehydes in the presence of a cyanide source to form alpha-amino nitriles in what can be considered a decarboxylative variant of the classical Strecker reaction. This unprecedented transformation does not require the use of a metal catalyst and provides facile access to valuable alpha-amino nitrites that are inaccessible by traditional Strecker chemistry.
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