期刊
ORGANIC LETTERS
卷 13, 期 20, 页码 5648-5651出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol202368n
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资金
- Nanyang Technological University [RG50/08]
- Ministry of Education, Singapore [MOE 2009-T2-1-030]
An efficient palladium catalyzed C-glycosylation of glycals with enol triflates has been established. The coupling reactions took place on the anomeric carbon, and the coupling products gave exclusively a isomers. The flexibility of the reaction was exemplified by the broad spectra of substrate scope, constituted of glycals protected with good leaving groups as well as an assortment of enol triflates.
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