期刊
ORGANIC LETTERS
卷 13, 期 19, 页码 5172-5175出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol202046y
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资金
- MICINN (Spain) [CTQ2009-09949, CTQ2010-16790, PTA2008-1524-P]
- FICYT [IB08-088]
A novel catalyzed intermolecular heterodehydro-Diels-Alder reaction between push pull 1,3-dien-5-ynes and aldimines or silylaldimines is reported. The sequence is promoted both by gold(I) or silver(I) catalysts and leads to the diastereo- and regioselective formation of 5,6-dihydropyridin-2-ones.
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