期刊
ORGANIC LETTERS
卷 13, 期 7, 页码 1674-1677出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol200169g
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资金
- NSFC [209-72027]
- Department of Science and Technology of Jilin Province [20100535]
- NENU [STC08013]
With a FeSO4/TBHP system in water, direct oxidation of sp(3) C-H bonds adjacent to nitrogen of arylureas to give both unprecedented tert-butoxylated and hydroxylated products 2 was revealed. Under elevated temperatures, either 2-oxo-N-arylpyrrolidine-1-carboxamides 3 or 1,3-diarylureas 4 were attained, depending on the aliphatic ring size of the arylurea substrates.
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