期刊
ORGANIC LETTERS
卷 13, 期 5, 页码 1154-1157出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol2000099
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资金
- National Science Foundation
- Alexander von Humboldt Foundation
Trimeric diphenylanthracene macrocycles were synthesized via the zirconocene-mediated coupling of 9,10-bis-[4-trimethylsilyl(ethynyl)phenyl]anthracene. The macrocycles feature a strained architecture due to orientation of the anthracene units into the plane of the macrocycle. The demetalated cyclophane exhibits a considerably higher flexibility in solution, while the zirconocene-containing macrocycle is quite rigid.
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