期刊
ORGANIC LETTERS
卷 13, 期 2, 页码 350-352出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol102674z
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-
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [19105002]
A rhodium-catalyzed 1,4-addition of sodium tetraarylborates to beta,beta-disubstituted alpha,beta-unsaturated esters has been developed. Highly efficient asymmetric catalysis has also been described to create quaternary carbon stereocenters at the beta-position of esters by tuning the ester group of substrates and employing a readily available chiral diene ligand.
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