期刊
ORGANIC LETTERS
卷 13, 期 3, 页码 434-437出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol102767j
关键词
-
资金
- National Institute of General Medical Sciences, National Institutes of Health [GM083944-03]
This paper describes the regioselective diamination of conjugated dienes using inexpensive Cup) as catalyst and N,N-di-tert-butylthiadiaziridine 1,1-dioxide as nitrogen source. The regioselectivity of diamination is likely due to dual mechanistic pathways which are greatly influenced by reaction conditions and the nature of the diene. A variety of useful internal and terminal cyclic sulfamides can be obtained in good yield.
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