期刊
ORGANIC LETTERS
卷 13, 期 17, 页码 4490-4493出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol2018328
关键词
-
资金
- Natural Science Foundation of China [20902113]
- Sun Yat-Sen Univeristy
The direct asymmetric intramolecular aza-Friedel-Crafts reaction of N-aminoethylpyrroles with aldehydes catalyzed by a chiral phosphoric acid represents the first efficient method for the preparation of medicinally interesting chiral 1,2,3,4-tetrahydropyrrolo[1,2-a]pyrazines with high yields and high enantioselectivities. This strategy has been shown to be quite general toward various aldehydes and pyrrole derivatives.
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