期刊
ORGANIC LETTERS
卷 13, 期 24, 页码 6560-6563出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol202874n
关键词
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资金
- NNSFC [21132005, 21121004, 20972161]
- MOST [2011CB932501]
- Tsinghua University
Regiospecific functionalization of tetraazacalix[1]arene[3]pyridines at the lower rim position of the benzene ring was achieved conveniently from their cross-coupling reaction with both aliphatic alcohols including chiral primary and secondary alcohols and phenol derivatives through the Cu(ClO4)(2)-mediated aerobic aryl C-H activation, which gave structurally well-defined aryl-Cu(III) intermediates and a subsequent C-O bond formation reaction under very mild conditions.
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