期刊
ORGANIC LETTERS
卷 13, 期 12, 页码 3235-3237出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol201140q
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资金
- NSFC [20932006, 91013007]
Rh(III)-catalyzed ortho C-H activation/olefination of phenol carbamates has been developed. High regioselectivity is observed with a range of phenol carbamates enabling efficient coupling with acrylates and styrenes. This reaction exhibits different reactivity as compared to the Pd-catalyzed ortho-arylation reaction of phenol esters and provides a new approach for the synthesis of ortho-substituted phenols.
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