期刊
ORGANIC LETTERS
卷 13, 期 18, 页码 4766-4769出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol2017033
关键词
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资金
- Robert A. Welch Foundation [F-1741]
Synthesis of an oxazaspiroketal-containing bissteroidal pyrazine is described. The key transformation of this synthesis involves stereoselective formation of oxazaspiroketal via aminyl-radical cyclization of primary amine lacking a radical-stabilizing group by Suarez hypoiodite oxidation.
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