期刊
ORGANIC LETTERS
卷 13, 期 14, 页码 3706-3709出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol201355t
关键词
-
资金
- French Ministry of Research [ANR-2010JCJC 7111]
Hemicryptophanes are host molecules with many applications as supramolecular catalysts or in ion selective recognition. A very convenient and efficient modular approach for the synthesis of hemicryptophane-tren (tren, tris(2-aminoethyl)-amine) derivatives has been developed. For instance, hemicryptophane 1 was synthesized at the gram scale in four steps from vanillyl alcohol compared to the previous seven-step procedure. The size, shape, and functionalities of the molecular cavity were also easily modified.
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