期刊
ORGANIC LETTERS
卷 13, 期 19, 页码 5302-5305出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol2021669
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资金
- National Natural Science Foundation of China [20832006, 21072211]
- National Basic Research Program of China (973 Program) [2010CB833206, 2011CB710805]
The first asymmetric synthesis of natural indole alkaloid (+)-decursivine was accomplished. The key step involves the PIFA-mediated intramolecular [3 + 2] cycloaddition of 5-hydroxytryptophan with a substituted cinnamamide in a highly diastereoselective manner.
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