期刊
ORGANIC LETTERS
卷 13, 期 9, 页码 2464-2467出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol200712b
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资金
- Rutgers, The State University of New Jersey
- US Department of Education
A dual-catalysis approach enables the small-molecule catalyzed kinetic resolution of allylic amines by acylation. By employing 2 mol % of each 4-(pyrrolidin D)pyridine (PPY) and a readily available chiral hydrogen-bonding cocatalyst, the first nonenzymatic kinetic resolution of allylic amines was accomplished with s factors of up to 20.
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