期刊
ORGANIC LETTERS
卷 13, 期 6, 页码 1370-1373出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol200057j
关键词
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资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Merck Frosst Centre for Therapeutic Research
- University of Toronto
Probing the nucleophilic ring-opening of various bicyclic [2.2.1] hetaryne-furan Diels-Alder adducts revealed that efficient reactivity could be observed with heteroatom nucleophiles by using a cationic Rh(I) complex in combination with a chiral Josiphos-type phosphine ligand. Remarkably, this catalyst system was not impeeded by the incorporation of a heteroatom into the substrate. Racemic materials afforded separable mixtures of enantioenriched regioisomers, indicating that strong reagent control is operative.
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