期刊
ORGANIC LETTERS
卷 13, 期 5, 页码 892-895出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol102926n
关键词
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资金
- JSPS.KAKENHI [20245022, 20655019]
- Toray Science Foundation
- NEDO
- Mitsubishi Rayon Co., Ltd.
- MEXT
- Grants-in-Aid for Scientific Research [20245022, 20655019] Funding Source: KAKEN
Bronsted base-assisted boronic acid catalysis for the dehydrative self-condensation of carboxylic acids is described. Arylboronic acid bearing bulky (N,N-dialkylamino)methyl groups at the 2,6-positions can catalyze the intramolecular dehydrative condensation of di- and tetracarboxylic acids. This is the first successful method for the catalytic dehydrative self-condensation of carboxylic acids.
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