期刊
ORGANIC LETTERS
卷 12, 期 23, 页码 5498-5501出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol102365e
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资金
- DFG
- International Research Training Group [IRTG 1038]
- Fonds der Chemischen Industrie
- Krupp Foundation
- Humboldt Foundation
The selective intermolecular anti-Markovnikov addition of carboxylic acids to terminal alkynes yielding valuable Z-enol esters has been achieved for the first time under rhodium-catalyzed conditions. The catalyst system is applicable to a broad substrate scope and displays a wide functional group tolerance.
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