4.8 Article

Pd-Catalyzed Carbonylative Conjugate Addition of Dialkylzinc Reagents to Unsaturated Carbonyls

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ORGANIC LETTERS
卷 12, 期 17, 页码 3760-3763

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AMER CHEMICAL SOC
DOI: 10.1021/ol1013476

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  1. NIH [GM 64451]

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The Pd-catalyzed addition of organozinc reagents to unsaturated carbonyls in the presence of carbon monoxide provides 1,4-diketones in good yield. The reaction was studied with a number of substituted cyclic and acyclic ketones as well as alpha,beta-unsaturated aldehydes.

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