期刊
ORGANIC LETTERS
卷 12, 期 13, 页码 3108-3111出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol1011955
关键词
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资金
- Oregon State University (OSU) Venture Fund
- National Science Foundation [CHE-0722319]
- Murdock Charitable Trust [2005265]
Organocatalyzed multicomponent coupling using a new ester-containing, proline aryl sulfonamide has been developed for accessing densely functionalized cyclohexenones, each containing a quaternary center in high enantio- and diastereoselectivity. In contrast to most enamine/iminium-catalyzed reactions, the use of molecular sieves was critical to optimum enantioselectivity.
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