期刊
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卷 12, 期 2, 页码 320-323出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol902620t
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Allylic sulfoxides, via [2,3]-sigmatropic rearrangement and oxidative addition of the resulting allylic sulfenate esters to Pd(0), are found to be excellent precursors of sulfenate anions. This hitherto unknown reactivity is applied in a new Pd(0)-catalyzed domino sequence Involving sulfenate anion generation followed by arylation to afford aryl sulfoxides.
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