期刊
ORGANIC LETTERS
卷 12, 期 1, 页码 200-203出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol902622b
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资金
- National Institute of General Medical Services [GM073932]
- Bristol-Myers Squibb
- Novartis
- NIH
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM074774, R01GM073932] Funding Source: NIH RePORTER
An enantioselective gold(I)-catalyzed Intramolecular [4 + 2]-cycloaddition of allenes and dienes is reported. The reactions allow for the asymmetric synthesis of trans-hexahydroindenes and pyrrolidine products using C-3-symmetric phosphitegold(I) and ortho-arylphosphoramiditegold(I) complexes as catalysts, respectively.
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