期刊
ORGANIC LETTERS
卷 12, 期 5, 页码 1108-1111出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol1001076
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资金
- Deutsche Forschungsgemeinschaft [SFB 623]
- Fonds der Chemischen Industrie
An enantioselective total synthesis of (-)-alpha-kainic acid is described. Key steps are an Ir-catalyzed allylic amination with a propargylic amine to provide an enyne and a diastereoselective intramolecular Pauson-Khand reaction. Subsequent steps involve a Baeyer-Villiger reaction, reduction of the resulting lactone, and direct Jones oxidation of a silyl ether.
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