4.8 Article

Novel Ratiometric Fluorescent Sensor for Silver Ions

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ORGANIC LETTERS
卷 12, 期 2, 页码 292-295

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AMER CHEMICAL SOC
DOI: 10.1021/ol902624h

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  1. Chinese Academy of Sciences
  2. National Natural Science Foundation of China [90813002]

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Incorporating azacrown[N,S,O] into furoquinoline fluorophore yields a novel ratiometric fluorescent sensor FQ-crown for silver ions. UV-vis absorption and fluorescence emission investigations indicate that FQ-crown bears the features of a large Stokes shift, about 173 nm, and red-shift up to 50 nm in the emission spectra and high affinity for silver ions (log K = 7.21) In ethanol in comparison with other competitive d(10) metal Ions.

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