期刊
ORGANIC LETTERS
卷 12, 期 22, 页码 5250-5253出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol102292a
关键词
-
资金
- Skaggs Institute for Chemical Biology
Organocatalyst-controlled asymmetric anti-Michael reactions of (tert-butyldimethylsilyloxy)acetaidehyde with a range of nitroolefins, followed by an intermolecular aza-Henry reaction with imine, provided iminosugar derivatives with five contiguous stereocenters in very high enantiomeric excess in one pot. The stereochemistry of the aza-Henry reaction was substrate controlled and is explained by a six-membered cyclic transition-state model.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据