期刊
ORGANIC LETTERS
卷 12, 期 4, 页码 700-703出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol9027144
关键词
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资金
- U.S. Department of Energy
- Robert H. Cole Foundation
- University of Tennessee Summer Undergraduate Research
Tetrabutylammonium tribromide (TBATB) has been found to be a unique bromodeboronation reagent for organotrifluoroborates. When compared to previously reported bromodeboronation methods, the mild and metal-free reaction conditions tolerate a wider range of functional groups. High regio- and chemoselectivity are observed in the presence of both unsaturated carbon-carbon bonds and aldehyde functional groups. An efficient synthetic route to (Z)-dibromoalkenes from terminal alkynes has been developed using the TBATB-mediated bromodeboronation as a key step.
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